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Crystal structure - Wikipedia

Unit cell. Crystal structure is described in terms of the geometry of arrangement of particles in the unit cell. The unit cell is defined as the smallest repeating unit having the full symmetry of the crystal structure. The geometry of the unit cell is defined as a parallelepiped, providing six lattice parameters taken as the lengths of the cell edges (a, b, c) and the angles between them (α ...

Synthesis, crystal structure, spectroscopic and hirshfeld ...

New asymmetrical azines, 1-((E)-(((E)-furan-2-ylmethylene)-hydrazono)methyl)-naphthalen-2-ol (I) and 1-((E)-(((E)-(1H-pyrrol-2-yl)methylene)-hydrazono)-methyl)naphthalen-2-ol (II) have been efficiently synthesized in very good yield in one or one, two pot synthesis pathway. The ligands structure was analyzed by; EA, UV–Vis, MS, IR spectroscopy and confirmed by XRD-mono crystal. IR spectra ...

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Synthesis and crystal structure of new monometallic Ni(II) and Co(II) complexes with an asymmetrical aroylhydrazone: effects of the complexes on DNA/protein binding property, molecular docking, and in vitro anticancer activity Y. Li, Z. Yang, M. Zhou and Y. Li, RSC Adv., 2017, 7, 49404 DOI ...

Which solid crystal structure is the most asymmetrical ...

triclinic, monoclinic, tetragonal refers to one of the seven crystal systems. The most symmetrical one is the cubic system and the least symmetrical is the triclinic one. Between those two extreme cases, you can find five additional ones. One of t...

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a, Conceptual illustration of direction-sensitive asymmetric optical camouflage by tuneable optical Janus effect b, SEM images of the nanostructured Au film and CYTOP nanopillars.

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Regiocontrolled dimerization of asymmetric diazaheptacene ...

The π-complex then collapses to form two asymmetric C–C bonds (2.326 and 3.246 Å) and generates the first transition state T 1 ... In contrast, the molecules in the thin film 5b exhibit dissimilar packing to the bulk crystal, indicating a new phase formed in the thin film. The thin films of 6a and 6b also exhibit a strong reflection peak at 2θ = 4.58° and 4.60°, respectively, which ...

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asymmetric crystal - definition - English

Example sentences with "asymmetric crystal", translation memory. hunglish. One consisted of a large lens surrounded by oddly asymmetrical crystal prisms. WikiMatrix. Pyroelectric charge in minerals develops on the opposite faces of asymmetric crystals. WikiMatrix. For example, when a wave travels through an anisotropic medium, such as light waves through an asymmetric crystal or sound waves ...

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Name the (1) most symmetrical and (ii) most unsymmetrical ...

Name the (1) most symmetrical and (ii) most unsymmetrical crystal system. Open 1 Answers 488 Views Education asked Jul 20, 2016 in Education by Freeshiksha ( 17,224 points)

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Two asymmetrical novel BTBT derivatives, namely TBTBT1 and TBTBT2, were synthesized adopting a new synthetic route and were characterized in OFETs. Besides the single-crystal transistor performance with maximum mobility of 0.24 cm 2 V -1 s -1 and 0.33 cm 2 V -1 s -1 , both compounds were found with higher vacuum stability than BTBT.

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Triboluminescence - Wikipedia

Triboluminescence is an optical phenomenon in which light is generated when a material is mechanically pulled apart, ripped, scratched, crushed, or rubbed (see tribology).The phenomenon is not fully understood, but appears to be caused by the separation and reunification of static electrical charges.The term comes from the Greek τρίβειν ("to rub"; see tribology) and the Latin lumen (light).

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Synthesis, characterization and crystal structure of four ...

In addition, the crystal structures of the ligands (2) to (4) were investigated by single crystal X-ray analysis. In the solid state, all ligands exhibited trans conformation about the –N =N– double bond. The Hg II complex (5) crystallized in monoclinic system with C2/c space group. The triazene ligand was found to be deprotonated prior to coordination and acts as monodentate ligand. The ...

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Co(II) Metal−Organic Frameworks (MOFs) Assembled from ...

Four asymmetric semirigid V-shaped tricarboxylate ligands have been employed for the first time to construct metal−organic coordination frameworks with the help of 4,4′-bpy, leading to a series of coordination polymers with diverse structures and magnetic properties. A series of four new coordination polymers, namely, [Co(HL1)(μ-4,4′-bpy)(H2O)3]n·(4,4′-bpy)n·(H2O)2n (1), [Co1.5(L2 ...

Synthesis, molecular structure analyses and DFT studies on ...

We then present a detailed DFT study based on B3LYP/6-31G (d, p) geometric structures of compounds (I); (II) and another compound (III) also another asymmetric azine (Z) -2 - [(E) -2-benzylidenehydrazine-1-ylidene] -1,2-diphenylethanone whose crystal structure is reported. The fundamental vibration wave numbers are calculated and a good agreement between the observed and calculated wave ...

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link.springer.com

Two new branched pentadentate amines (N5), 3,6-bis(2-pyridylmethyl)-5 methyl-3,6-diazaheptane diazahexane-1-amine (1) and 4,7-bis(2-pyridylmethyl)-6-methyl-4,7-diazaheptane-1-amine (2) have been prepared. These have been used for the synthesis for the eight new macroacyclic Schiff base complexes, by template [1 + 1] condensation of pyridine-2-carbaldehyde or O-vaniline and amines (1 and 2) in ...

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